some_origins_of_multiexponetial_decays_for_single_dyes
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some_origins_of_multiexponetial_decays_for_single_dyes [2019/03/06 12:43] – admin | some_origins_of_multiexponetial_decays_for_single_dyes [2019/03/06 12:44] – admin | ||
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//Case A) The constant kAB is too slow with respect to $\tau_A$ and $\tau_B$.// In this case the compound A would decay to the ground-sate before the excited-state reaction could take place. The decay measured would be single exponential and coincident with $\tau_A$. | //Case A) The constant kAB is too slow with respect to $\tau_A$ and $\tau_B$.// In this case the compound A would decay to the ground-sate before the excited-state reaction could take place. The decay measured would be single exponential and coincident with $\tau_A$. | ||
- | //Case B) The forward reaction constant $k_{AB}$ is fast, but the back-reaction constant $k_{BA}$ is too slow in comparison to $\tau_A$ and $\tau_B$.// In this case the decay time measured in the spectral region of A would be single exponential, | + | //Case B) The forward reaction constant $k_{AB}$ is fast, but the back-reaction constant $k_{BA}$ is too slow in comparison to $\tau_A$ and $\tau_B$.// In this case the decay time measured in the spectral region of A would be single exponential, |
Note that this situation is the typical case of dynamic quenching with the particular case that the product being formed is fluorescent. | Note that this situation is the typical case of dynamic quenching with the particular case that the product being formed is fluorescent. | ||
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A situation like this may occur with molecules dissolved in an aprotic but hygroscopic media, like acetonirile. Water molecules may diffuse (diffusion happens in the nanosecond time scale) and react with fluorophores bearing proton-transfer groups like -OH or -NH2. | A situation like this may occur with molecules dissolved in an aprotic but hygroscopic media, like acetonirile. Water molecules may diffuse (diffusion happens in the nanosecond time scale) and react with fluorophores bearing proton-transfer groups like -OH or -NH2. | ||
- | //Case D) Interconversion rate constants | + | //Case D) Interconversion rate constants |
This situation may happen if compounds A and X were directly in contact prior to excitation, for example throgh ground-state interactions. | This situation may happen if compounds A and X were directly in contact prior to excitation, for example throgh ground-state interactions. |
some_origins_of_multiexponetial_decays_for_single_dyes.txt · Last modified: 2019/03/19 12:31 by oschulz